i see Tx Rx on pinouts so it should work with SSC 32 if provides COM port connection via bluetooth
but first of all you will need to setup it with AT commands
also seems to be yours have no internal 3,3V regulator so do not connect power directly to SSC
no worries, i was newbie in that too and i could say still not a magician
if you’ll go trough tutorials from beginning of topic: SSC-32 provides 5V of power to BT module
yours require 3,3V so 5V is too much for it. you will need to put LM1117-3.3 chip between to make 3.3V from 5V
thats first case
BUT before you start to play with if find a manual, pdf or something for your module because i see VCC pin there too so there is a chance that it work with 5V too and 3.3v pin is an output
other one is BT module setup - usually it goes via com port and terminal program like hyper term or other.
AT commands will depend on core(firmware) of your BT module, usually there should be something about in manual for your BT module.
AT command itself is just a string sent from terminal to module. usually as first module should be in AT mode.
i saw dip switches on yours one seems to be responsible of putting module in AT mode
i’m using BTM 222 module so my AT’s looks like that
PS
yeap at the page you provide i see datasheet at the bottom, your device accept 3.5-8V so you can connect as in the tutorial but firs connect to PC via comport (not radio, and probably you will need a TTL->RS232 converter here like max232 chip) and make base config via terminal (remember about baudrate, usually default for BT is 9600).
i see few AT commands in this documentation.
if both GND pins are connected together on module you do no need to connect additional wire.
most probable reason of 2nd GND pin is - one required for power and second for RS232 transmission.
but when you connecting BT module to SSC, RS232 GND and power GND are connected on SSC so if on BT module they also connected 1 GND wire would be enough.
if not just connect it together and put 1 GND wire to SSC GND
3,3V pin on your BT module seems to be an output so you can power something else from BT module (something with low power consumption definitely)
if you don’t need to power something else with 3,3v just leave it unconnected